From the Hand-Book of Artillery:
55. State how to unspike a piece.
If the spike is not screwed in or clinched, and the bore is not impeded, put in a charge of powder ½ of the weight of the shot, and ram junk wads over it; laying on the bottom of the bore a slip of wood, with a groove on the under side containÂing a strand of quick-match, by which fire is communicated to the charge. In a brass gun, take out some of the metal at the upper orifice of the vent, and pour sulphuric acid into the groove, and let it stand some hours before firing. If this method, several times repeated, is not successful, unscrew the vent piece if it be a brass gun; and if an iron one, drill out the spike, or drill a new vent.
I would try drilling it out and go from there.