#1). They used to sell a "blue remover" that said on the bottle that it was pure nitric acid. This assumes you have a real "blue" and not some paint or other more modern coating process finish. That might resist acid. I thinned the blue, fortunately on a concealed part of the gun, with plain old "GUNK" grease remover... And if you get real desperate... "grit" will remove anything. Sandpaper. Rouge. Valve grinding compound. Emory cloth. Everyone will tell you that the "quality" of a "blue job" is determined by the skill of the person using the "buffing wheels" to polish the metal before blue is applied...
Rust prevention in non stainless is another story. HARD!. Steel compounds want to rust/ react with oxygen in air. [FYI all metals "oxidize." Other metals, like lead or aluminum, form a one layer, TIGHT SEALED, layer of oxidation that stops the process. Only iron based compounds like steel form a porous "oxidation" / "rust" that permits oxygen to get thru the layer to continue the process. That is why the shiny, new cast lead bullet is dull grey the next morning...] Blueing is a form of controlled rusting. Oldest and most obvious is lots of oil/grease constantly re applied. Real pain. Then there are other organic compounds. Rosin from trees. Lame compared to more modern. There are clear paints. Brass was coated with shellac to keep it shiny, then lacquer. I understand that todays auto products are finished, final coat(s) with a clear, plastic material. Stout finish, but a pain to refinish if scratched. Your call.
#2). If you think you want the hassles of "gun smithing" then visit brownells.com and start to decide on a speciality. Shotguns? Target rifles? Handguns? FIRST, get the FFL (Federal Firearms License) application kit from ATF (Bureau of Alcohol, Tobacco, and Firearms --if not in yellow pages or front of phone book, call FBI and ask. They work together... Without the paperwork, you could be found guilty of a felony and barred from every working on OR OWNING guns... ) There us much to learn. Apprenticing with a specialist in your chosen field is a good place to start. Basically, a "gunsmith" is a machinist/woodsmith (finish carpenter/cabinet maker) with an FFL.
If your passion still rages, "good luck."
Oh yes, most community colleges have courses in "machinist" and "wood working" mighty cheap. Might not let you work on guns but teach you the basics.