Can you? yes. Should you??? Welllll....
You can throw in an intermediate step. .270 is handy. .280 Remington also works. Makes the trip into full length .25/'06 slightly easier.
Of course, lube well with a good lube. Lanolin is the ancient standard. Lee washable is about as good IMHO.
If you set the .25/'06 full length die with many trips by the first case into the gun so it closes "tight" you should have minimum headspace/maximun case capacity and less case "work hardening," stretching, etc.
If you want longest case life, an anneal is appropriate. Dip neck in molten lead, PURE LEAD, --hold by rim with fingers and you will know QUICK when to drop into water-- OR buy the propane heaters and templac or templac stick or...
As suggested, .270 is .27/'06 and .280 is .28/'06... Since Uncle Sam no longer leaves free brass laying around, buying any one of these makes perfect sense when you see a deal. No reason you have to use .30/'06. And as is the case, usually, if you try around, your gun will show a preference and get you just that little better performance that makes us handload anyway... happy holidays, luck.