... it's VERY unlikely you are driving PPCB's too fast. Col Harrison's write-up in the Rifleman contained PPCB loads for the 300 Win Mag that fully equaled factory power and accuracy. In fact, one of his co-workers seriously offered to use them in long range rifle competitions.
More probably, you are just exceeding the velocity limits for your alloy. Col Harrison noted that for best results, the alloy and load should be ballanced, harder alloys for hotter loads. The trick is to get a little bit of base upset when fired, but not enough upset to make a blob out of the PPCB.
You can probably get a copy of his article for the trouble of a phone call to the NRA.
HTH
kbmoly