As you know rifles are a law "unto" themselves, and what works best in a paticular rifle might be different that what "should" work best. FFFg will sometimes work better in a bore that "should" work best with a more coarse powder. And then mixing brands of powders confuses things even further.
Case in point: I have large bore musket (.75") that "should" work best with Fg. But, with Goex, Fg doesn't work worth dog-doo, FFFg does. However, I got some Swiss FFg, and that works best yet.
Then of course when you start changing patch, lube, and wads things change again, and I have a lot more experimenting to do before I find the best combo for that gun. But right now the FFg Swiss, and a wonder wad under the patched ball seems to be the most promising.
So yes, even though this person may have been shooting a bore size that "should" work best with FFg, it could indeed shoot best with FFFg, depending on his projectile, Powder charge/velocity/power level, lube, patch, rate of twist, etc. etc.