Live catch trap. Get a tarp that completely covers the trap. Fold the tarp up and back from the entrance. The rest of the trap should be completely covered. When picked up the the tarp should drap and hang down below the trap. Only the entrance to the trap should be open. Get a fresh can of tuna fish and bait the trap with that. If you have a place where they are going under the house. set the trap right beside that location and up against the the foundation.
When you capture the culprit, flip the tarp down to cover the open end and carry the trap away for disposal. The skunk should never see you
You will be very lucky to ever catch the one you released again.
Back a hundred years ago when I did fur trapping, the local dog catcher would call me to catch skunks and racoons in the city. I caught a lot of skunks way back then at $10 a skunk.