CW:
2F will have lower pressure than 3F for the same effect.
Something else about powder... if you are buying "A" Blasting or Fireworks powder the fuller designation is to use F
a whereas sporting black powder is designated as with F
g. 4Fa is approximately equivalent to one Fg in formulation, granule size, and density and is usually purchased in 25# or 50# quantities for a few dollars a pound cheaper than the sporting grades and is usually only available from a GOEX powder distributor. Sporting grades are available in one pound cans and 25# boxed bags and are more redily available from sporting goods stores as well as the distributors.
Here are some fairly close approximations:
4Fa approx. equiv. to Fg
5Fa approx. eqiv. to FFFg
7Fa approx. eqiv. to FFFFg
I have copies of the old "through" vs. "on" sieve specs for the various black powders (sporting, "A" and "B") from DuPont... GOEX is using the same specs but has discontinued the "B" blasting (sodium nitrate oxidizer versus potasium nitrate in "A" and Sporting). "B" was considerably cheaper but was slower and gave less pressure. With the expanded use of ammonium nitrate for blasting, "B" demand almost disappeared.