FFFg is fine for your .32. I've found that it works well for priming in flintlocks too, although FFFFg is better.
Pyrodex used to have a rep for not working well with a flintlock ignition. I've known many who use a duplex load. 5 to 7 grains of black powder as an initiator, if you will, then the main charge of Pyrodex, reduced by that same 5 to 7 grains.
Personally, I've never seen the attraction of the substitutes other than that they are more readily available at local gun stores. It is not any easier to clean. It is just as corrosive, so it just doesn't seem worth it to me.