With any new (to me, brand new or used) I give the barrel a quick solvent clean and dry it, then start shooting.
As to getting on paper, set up a target , I like those 'scope sight-in ones with the 1" squares, but anything you have will do, at about 50yds., open the action and bag or box the gun . You look down the bore at the target center and adjust the scope to see the same spot. Remember that when doing this you adjusted the scope adjusters opposite of what they say; ie, go Left to adjust to the right. I usually find that the elevation is a little low when I go to shooting real ammo, but its on the bull and windage often is really close.