Will, are you sure that you really want to open this can of worms???
If you weighed it at 40 grains, it is 40 grains. If you drill a hole in an antler tip that holds that pan of powder exactly then thats a 40 grain measure. When you change powder, there is probably some small difference in density so when you fill the horn tip measure exactly the same, then that's 40 grains of powder even when you poure it on the scale and it measures 41.
Some folks will tell you that you have to use the volume measure others will tell you you have to use the scale.
For what it's worth, I've had my best results with volume measures.