recondoc,
The cylinder should not turn when the revolver is uncocked. The little bolt (part number 37 on the large frame I believe) in the bottom of the frame in the cylinder window is probably malfunctioning. It could be that the sping that lifts it into position is broken, or it could be that there is a piece of fouling or something keeping the bolt from moving into place as it should. When you cock the gun, the hand that rotates the cylinder is holding the cylinder in place, but it is critical for the bolt to work also or you could get into a real problem. You could break the hand if you continue to shoot it that way or much worse. The good news is, that it is probably not too expensive or diffcult to replace and the parts should still be avaiable from Dan Wesson. As far as I know, no revolver cylinder should ever spin on its own whether the gun is cocked or uncocked. I would take it to a competent gunsmith if you have ANY qualms about fixing the problem yourself and I would not fire the gun until it was fixed.
Roll Tide