It has long been a practice to add a wee bit of smokeless powder next to the primer, before adding the black powder. This was done to reduce fouling.
Typically it was done in large-bore cartridge guns that held a lot of powder, such as the .45-70 or .38-55.
However, I can't recommend it. Before World War II, people were doing this and using bulk shotgun powder. Today, many of the powders used are long gone. Some shooters also used quick-burning powders such as Unique and Bullseye but I surely don't recommend this!
To my knowledge, the use of ANY amount of smokeless powder in black powder is forbidden in black powder cartridge rifle competition. It will get you disqualified or permanently banned from competition.
Then there's the know-it-alls who use small doses of smokeless powder in their muzzleloading rifles and cap and ball revolvers, before adding black powder. These types often end up wearing a puzzled look, standing at the entry to the ER or the Pearly Gates.
Under no circumstances should you use any amount of smokeless powder in a black powder firearm not designed for smokeless powder. And a pox on Savage for introducing that abomination --- a muzzleloading rifle that shoots smokeless powder. For that, they should get a cancer! :twisted:
In strong cartridge guns --- such as the Marlin 95, Ruger No. 1, Browning or Winchester 1885 --- you should be able to get by with adding a bit of bulk powder but what's the point?
After all, you still have to clean the cases and bore thoroughly after use.
As for shooting cleaner, if you can't get a black powder rifle to shoot halfway clean then you need to change your loading technique, powder, bullet alloy, bullet lubricant, bullet size and a host of other variables.
I find that in my .45-70 Trapdoor, I get clean loads by using Goex FFG, a greased felt wad on the powder, a soft lead bullet sized to .459 inch and a home-brew lubricant (search my name, I've listed the recipe ad nauseum in here and elsewhere).
I've never found the need to add smokeless powder to my black powder loads.
Frankly, the whole practice makes me nervous. More than a few guns have been blown up because the loader didn't realize he charged the case two or three times with a smidgen of smokeless powder, before seating black powder.
It's very easy to do: 4 or 5 grains at the bottom of a long, .45-caliber rifle case doesn't look different from 8 to 10 grains or more.
Id' steer clear of the practice.