The 7,62 nato and 308win are different rounds. The 7,62 nato has 40k breech/chamber pressure and the 308win has 52k+ in chamber/breech pressure. After checking the headspace on the enfield it should be able to handle both rounds. I have heard that some of these enfields can be very accuturate if you get one in good condition(bore). The fun is figuring out what it likes to eat to be accurate sometimes its not a given with every gun even some of the swiss rifles have been known to have accuracy problems too. I have heard great things about the latest mosin sniper 91/30's being offered too. There accuracy is awesome too. I like them all.
Becareful with "308" rifles there are 308win, 7,62 nato and 308 cetme. Some of the 7,62 nato rifles have fluted chambers so the 308 win round shouldn't be used in them because of the thinner walled case.(cetme)
The higher pressure 308win in a 7,62 nato fluted chamber can cause a serious accident if the case ruptures in the chamber. If the rifle says 7,62 nato i only shoot 7,62 nato out of it just to be safe with the lower pressure round in the semi-auto's.