It is a potentially dangerous technique. The story I have is that Elmer Keith demonstrated worked up some examples and got small but arguably significant (also arguably insignificant) improvements in velocity for 50BMG ammo during WWII. The concept was expanded to other cartridges and there were some dangerous detonations that caused destruction of the test guns. The conclusion was that the techique works, but really complicates case manufacture, yields only slight improvements, and could yield dangerous ammunition. The idea has been dropped since then.