S&W started their long and distinguised side-swing out cylinder revolver line just over a century ago with the design finalized as the "military and police" model in .38 special caliber or the K frame size as we know it today. It was the basis for the S&W models 10, 12, 13, 14, 15, 16, 17, 18, 19, 64, 65, 66, and 67 models in blued steel, stainless, and aluminum alloy. Variants exist in .22 LR and .32, and 9mm calibers.
The N frame got started as the "new century" model which became the .44 frame size, and is noted for it's thicker, beefier cylinder and frame dimensions compared to the K frame. It formed the basis for various models including M1917, M20, M21, M24, M25, M27, M28, M29, M57, and thir variants in blued and stainless steels. The cylinder and frame proportions are distinctly larger than the K frame in both standard (.38, .357, .41,.44, and .45) and magnum calibers.
The L frame started with the 486, 586, and 686 series in .357 caliber. Beefier than K frame, but sharing the trigger and grip sizes with K frame.
I guess what it comes down to is familiarity with seeing enough of these guns to spot the frame/cylinder proportions, and identifying details of the barrel, sights, and grips.
HTH
John