True silver solder is a form of brazing. There are several "low temperature" Silver Solders in the hardware stores that are not true silver solder, but are actually lower temperature than tin/lead solder. They are not even close to being true silver solder, and will not adhere to stainless at all (I've tried it), perhaps not even carbon steel, they do work on brass. Avoid them.
You will probably have to find real silver solder at a welding supply or hobby shop, and the proper flux as well, which is quite different from lead solder flux, it is more akin to brazing and welding flux. It melts down into a glass-like crust. There are (or used to be, as I haven't done real silver solder in 30+ years) three temperatures of silver, low, medium and high, to allow joints to be made close together without loosening the previous joint. (start high). There's a few hundred degrees between them.
Silver solder is the most common method of attaching front sights that aren't dovetailed or staked in place. Particularly most common on a Single Action Colt or clone. Unfortunately, the temperature required (dull red steel) of silver solder requires a reblue on a non stainless gun, and a repolish to remove the heat marks on the stainless. Be carefull not to apply too much silver solder or it will run or fillet too much and make a brass-like outline around the joint that isn't professional looking on a blued gun. One of the problems with some front sights, which I've heard more complaints aimed at Pietta, is they use too little solder, probably trying to prevent the solder showing against the blue, and the sights get knocked off too easily.
Silver solder can be done with a propane torch, you don't need a welding torch, though, if you're careful, you can use one.
Apply the flux between the parts to be joined, heat the metal parts 'til the flux melts, apply the silver solder wire to an edge of the joint opposite the torch, and when it melts, it should flow toward the torch. Aim the heat the largest part with the torch flame as if you play too much heat on the smaller part you'll overheat it
Silver solder is also available in a jar of ground solder powder mixed with flux as a paste, and for many applications is easier to use, as when the temperature reaches the melting point, it flows and you're done. Of course the parts have to be clamped together some way to hold them in position through the process.