Personally I'd hesitate to comment unless I examined the item in person, but then I'm no metallurgical expert either. One issue that bowling ball mortar makers need to keep in mind is that commercial gas cylinders are manufactured and tested in a certain way for holding compressed gases under certain conditions. The folks who use them more or less "as is" and only cut down are taking advantage of the original features, materials, heat treatment, etc.
I would be a bit concerned that welding on these cylinders without thinking through the details of what the welding heat does to the original heat treatment, could weaken the cylinder. Maybe these cylinders, even if unevenly annealed, are strong enough for BB mortar use when using small powder charges, but I don't know. Just keep in mind that the more you change it from the way it was made, the more unknowns you introduce.
Since the use of BB mortars seems to be increasing, I'd like to see a competent engineer go through the math of gas cylinder design specs vs. their use as BB launchers. That means to me using the hoop-strength formulas that are typically used for gun barrel design, and applying them to commercial gas cylinders. The immediate objective would be to analyze a typical gas cylinder and determine, by the hoop strength formulas, what the maximum pressure is that they can withstand, using typical safety factors of say 2:1 or more. Then I'd like to see what internal pressures we're dealing with, given various types and weights of black powder.
I've been out of school too long to feel competent to do this, but I'd really like to see someone go through the numbers here.