If it melts at around 450 degrees F, then it is silver bearing soft solder not what is usually called silver solder. Silver solder is more of a braze, and depending on composition can melt at as low as around 900 degrees F, but more commonly at around 1100 - 1300 degrees F. Or at least that's what I thought I remembered from metal shop, and just confirmed with a bit of Googling... ;-)
Hard to say what exactly was used to attach the sight, it might be worth a shot at heating to 500. But if I were you I'd probably take it to a good gunsmith, he might be able to give you a better idea of what it would take after looking it over.
Just a Shooter