Try this: measure the chamber mouths, I'll bet you a nickle they're smaller than your groove diameter, seems to be a common ruger malady. Mine do the same thing with smokless powder. Bullets are being swaged as they leave the chambers, and skid down the barrel. chambers can be honed, in many cases this has helped. If that is the problem, it's a nusiance, but easily fixed. Another alternative is to use black powder, you won't have the leading problem.