What you are talking about is not reaming the necks, but rather cutting a throat. And both those cases are going to require custom throaters. You MAY be able to use an off the shelf 303 Brit throater for the 32-20, but I am not aware of anything existing that would work with the 32 spl. I think the bore size of that and a 8mm are different enough that it wouldn't work.
You could have Dave Manson make custom throaters for you, they are around $100 each, then it's just a matter of having a good gunsmith use them properly to do the job.
The actual cutting is not exactly an easy operation, because throat reamers like that have a nasty tendency to chatter. Unless you are extremely careful with your setup you can end up with a very odd looking throat when you're done.
Were they my guns, I would likely figure out a way to load around those throats, since both cartridges normally can be very accurate with cast bullets when fed the right bullets and loaded properly. Lyman #3118 in the 32-20 and the Ranch Dog 32 spl. bullet in that are a pretty good start and likely can be made to work well. Remember 30-30 has no real throat either and normally is extremely accurate with the right bullet and load.