With a stout round nose (domed) pellet you should only need about 15 fpe for good head shots. A .177 at or around 1,000 fps will penetrate very well. A .22 cal at around 850 fps will deliver a bit more energy, and with a good pellet and proper placement will work just fine. The slower .22 will be quieter (not even close to the sound barrier) and cause a larger wound channel, with a hollow point like the Beeman "Crow Magnum" pellet over penetration would not be a concern either.