It is indeed possible and safe to build a double rifle on a shot gun action. Most American shotguns are too weak and lack one or more of the needed features for a strong double rifle. You need an action which has a third fastener such as a Greener cross bolt or a hidden fastener.
As for the pressure you can figure out the pressures,and weather the exceed the original proof load by finding the head area of the cartridge you want, and comparing it to the head area of the original chambering.
In any case you will probably have to bush the firing pins and for get the sleeving idea, use the mono block and build new barrels from there.
However you do it if you value your life RE PROOF the gun!!!!!
There is a very good book on building double rifles on shotgun actions and this is Building DOUBLE RIFLES On Shotgun Actions by W. Ellis Brown. It is not cheep, something like $49.00 but well worth the money.