The military uses primacord as an explosive by lighting both ends, so I am told. When the two flames meet somewhere in the middle it makes the primacord detonate instead of burn.
Primacord (aka detcord) is actually a plastic high explosive (PTEN, RDX or some others) that is first encased in a textile yarn and then covered by a plastic and yarn sheath for waterproofing. It only needs to be initiated at
one end by a blasting cap and burns (detonates) at about 25,000 fps. I've used a bunch of it. Neat stuff and very safe. A few wraps around a tree and it's better than a chain saw. Faster and more fun too. :-D
What happens in a firearm, supposedly, is if the powder fills less than half the case, the primer flash shoots over the top of the powder charge and ignites both ends of the charge. When the two flame fronts meet it makes a detonation instead of just burning, which can blow up rifles.
What about the fact that when reloading, there are many proper charges in which the powder doesn't come any where near to filling the case? Smokeless powder burns very rapidly and produces gas. It can't be made to detonate like a high explosive. If it could, we wouldn't be allowed to buy it.
The amount, type and burn rate of the powder determines how much gas is produced which determines the internal pressure on the chamber. IMR4895 is the standard powder in .30 caliber (30-06) military ammunition. How could a 10 grain charge possibly produce more gas (ie: pressure) than say a 25 grain charge?
I won't state for a fact that there aren't other ways, but the only things I know of that can KB a rifle are either a massive overcharge of powder (unlikely due to case capacity), the wrong powder (very possible), a plugged barrel (definitely), completely FUBAR headspace or a round firing with the bolt out of battery (both possible).