Well, heres an idea that popped into my head. Its very poorly developed at this stage but it seems like it might work (to me at least) so I thought I might as well post it on this forum where there are lots of people who actually know what theyre doing.
Summarized Idea
My thought was that the powder burn would release quite a lot of energy in the form of heat. It is my understanding from what Ive read about powder launchers thus far that this heat is basically wasted; it goes to heat the barrel, projectile, air, etc. I thought that perhaps this otherwise wasted heat could be used to boil some water and create some more pressure to launch the projectile with greater speed.
Technical Explanation and Justification of Idea
The idea, then, would be to utilize the heat that would otherwise be wasted in some way to launch the projectile with (hopefully) greater speed and thus better range. Given that the barrel in question is about 2.5 feet long and about 2.7 inches in diameter, this gives a volume of about 172 cubic inches or about 2.8 liters. From what I remember of my chemistry classes 1 mole of water gas, which weighs about 18 grams will occupy 22.4 liters at 1 atmosphere or about 14.7 psi. Ive calculated (though imperfectly) that the energy needed to heat this water from 70ºF to the required 212ºF will be about 1440 calories. From the same series of calculations, and Googles best guess as to the amount of energy released by the 1 ounce of gunpowder I plan on using will be approximately 26,817 calories, most of which, I assume, would be released as heat.
Would it be a good idea to perhaps use a balloon or other separation device to hold some water to be boiled by the heat of the powder burn? If my calculations are correct then there would be plenty of heat for at least 54 grams of water to be boiled rather instantaneously. This would produce 67.2 liters of steam under normal pressure, but of course the barrel, right before the projectile exits, would have 24 times less volume, hypothetically producing a pressure of 24 atm or about 353 psi in addition to the gas produced by the powder burn itself.
This seems like an easy way to use the heat already being produced by the burn to give me longer range or better fuel efficiency (defined, in my case, as the percentage of energy from the fuel that actually contributes to launching the chosen projectile). It would also have the effect of cooling the reaction and reducing the thermal shock the barrel would have to endure, hopefully prolonging its safe service life.
What are your thoughts on this? Is this even worth attempting?