Difference in chamber dimensions (from .223 go gage to 5.56 field gage) is minimal (about .005" I believe, but don't quote me on this.)
SAAMI spec is about 55k psi for .223 and NATO spec for 5.56 is about 63K. You should be able to safely shoot a .223 round in a 5.56 military gun, but should not, according to the experts, shoot a 5.56 military round in a .223 Remington. I have three contender barrels in .223 and they do not know the difference in the two rounds. No problems firing or extracting. I have heard other folks have a heck of a time getting fired 5.56 brass out of their .223 contender barrels.
Most modern .223 firearms will withstand the pressures of the 5.56 round. There are some inexpensive guns that are a little loose on tolerance that I would be very careful with and look for pressure signs before firing many rounds. Some people feel that due to the smaller case and chamber, the gun has more metal in the barrel and receiver so is therefore stronger. Not necessarily true. The 5.56 NATO is pushing as much, if not more chamber pressure than the 7.62 NATO round. Yep, more pressure than a .308 Winchester.
If you have a modern rifle that is made on the same action as some of the 65k psi cartridges like the 300 WSM, I don't see why you can't shoot the 5.56 loads. My suggestion would be to call the Mfg and talk to the engineer. If you can confirm the barrel and action go thru the same heat treating process and are made to same mfg spec, you should be golden. Again, talk to the manufacturor to confirm fabrication or manufacturing specifications on action and barrel strength.
Good luck, but stay safe.
Steve
