Is anyone else the least bit nervous about the weld ringing the barrel right over the powder chamber on the 90mm tank barrel
Really hard to tell, I can't see any weld, maybe you are assuming there must be one at the front end of the reinforced section?
This is kind a krazy looking rig, but it might shoot well. As for safety, you would have to ask the maker how it was put together, where the welds were, what kind of welding was done etc. I've tried to weld modern military cannon barrels using ordinary electrodes and it did not work well, I got no penetration. You need some trial and error and the proper composition of electrode, not to mention enough amps to get the penetration required for a strong weld.
I like the modern military cannon barrels because they were designed for much higher interior ballistic pressures than you will get using black powder. Don't get overconfident though since the weak point will usually be any welding you do that isn't optimized for the particular alloy that the military gun barrel happened to use. I have some 30mm barrels from the A-10 Warthog aircraft, and they are made of such hard steel it is all I can do to cut them, much less weld them. I have to use an abrasive chop saw, the guillotine bandsaw won't even scratch these barrels even when I use the more expensive bi-metal blades. These barrels were already de-milled (chambers cut off and destroyed) before I got them, it wouldn't make economic sense to destroy an intact, chambered barrel.