Fairly easy. Cerrosafe is a standard alloy, bit costly, but permanent unless you beat it up, mail it... etc. Any machinist can measure and tell you fairly exact measurements.
Cheaper, garden sulphur. Yup, the mineral. Cheap at any garden store. Melt it. Outside is good. If it catches fire, it STINKS. No danger, just slip the lid on to put out the fire and turn down the heat. Plug the barrel with a tight patch ahead of chamber. Squirt of WD40 or the like doesn't hurt. Pour into chamber--funnel helps, let cool minute or three and GENTLY push out. If you break it, do it again. Big deal. Any machinist can measure this too and tell you what you got. Or you can hold it up to pictures of cartridges.
There is quite a list of .222 diameter sized rounds. (Also diameter of many 9mm's.) Some European ones get quite long and brass is scarce. With .204 Ruger on the .222 Mag case, I think, brass shouldn't be too hard to find/make. LUCK.