So I haven't opened a can of worms in a while... and I hate the word overbore... so here it goes. This term is rampant with big cased medium bore rifles.
There are no "overbore" cartridges in existence.
The word overbore by definition means overcome by physical force. This reference in firearms usually refers to giant cases and small bullets. Cue the 7mm ultra mag which I have some years of experience with, the .50 BMG which of course has more powder than them all, and rounds like the small 223 super short mags and such.
So why do peoples perception of these big cases and small bullets make them somehow think that there is something intrinsically wrong with the cartridge just because it is slightly more inefficient? When in reality any gun out there that is running less than 60,000psi could be considered less than efficient by a modern standard. There seems to be some belief that they aren't burning all their powder, or we are shooting this bullet out of a barrel that is way too short, or any number of excuses to discount the fact that a big cases makes a whoooole bunch of pressure and make bullets shoot rreeeeeeeaaalllyy fast! Which is good in my mind.
The reality of it stands that powder is burnt in the first couple of inches. So unburnt powder is just right out. Some powders do leave residue, but that isnt unburnt. Compression under the bullet makes so much heat when that round goes off, there is no way for the combustibles to last more than half a nanosecond.
Then as the bullet accelerates - wouldn't you want as much pressure as humanly possible? I want that pressure curve to shoot right up to sammi spec! And i want it to stay there! And the bigger the case, the more in^2 for the pressure to build on, the more total pressure, the less drop in pressure down the barrel. So what if you bullet exists the barrel and you are still in a high part of the power curve? Does that mean anything? Do you get more muzzle blast? Yes. Do you get more recoil? Yes. Do you get a bigger fireball? Hell yes! And what is wrong with all of these things? Nothing. If there was a problem with them we would all be shooting .22's for fun and everybody would hunt with bow and arrow for deer (not saying there is anything wrong with that)
Why do you have to try and make a level at which there is "too much" left over pressure? There has to be left over pressure. You aren't going to use it up. If you are at the 0 mark when your bullets leaves the barrel... you got some problems! Every gun has muzzle blast. It's what they are made for! BOOM! Higher average pressure = more acceleration. Simple.
I just get annoyed when people say my 7RUM is "overbore" or my .458 lott is "overkill" because I'm up at 60% on the power scale when my bullet exits the barrel and your 7mag or 45-70 is down at 20%. (not scientific numbers, FYI) I'm glad you are using less powder and all of that... but I care about POWER. Raw speed and energy. I don't care how I get there. I'm an big American meat eating capitalist!
Is the speed harder on barrels and ears and your face? Yeah, it is. But there is nothing about which goes to the point where anything is actually physically overcome by the force of it.
If anyone can show me a cartridge in which the pressure scale goes to and stays at 100% of sammi maximum before it exits the barrel, then I will agree that there is something that is actually "overbore" and cannot gain in velocity. But this doesn't exist, and you would have to have such a ridiculously slow burning powder to do this in the first place. I agree that there are diminishing returns with such large case capacities, as pressures can only get so high, but there is still a gain along the pressure curve as it drops more slowly. If you did take the same case or a bigger case, and increased the maximum pressure rating, what is the result then?? Higher acceleration and... More velocity!!! Yay!!
So yes, certain cases are less efficient than others. But as long as there can be increased pressure ratings, change in barrel twist, and good bullet design, there is no case - and will be - no case of which their powder capacity outpaces the physical limitations of the firearm and bullet.