R,E,A,L, bullets first as said they should be as close to pure lead as possible, no patch. If I remember correctly the REAL stands for Rifling, Engaged at loading, most of the thick commercial muzzle loader lubes work good, I have used plain old Crisco baking grease. With both Lee REAL bullets and Lyman MAXI Balls neither uses a patch.
As to the Lee pistol mold, the WW should be good for mid-range loads in the 44. Lee states their bullets may or may not need sized, several things go into the actual drop diameter of a cast bullet. In any case you want to use a good lube. The Lee liquid tumble lube works well for many. I would not use a spray lube on any cast bullets. You will get gas cutting and barrel leading.
A very good investment for a new caster is the Lyman cast bullet manual.