In general, the 25 ACP will feed more reliably since it was designed from the ground up for a self loader while the 22 LR wasn't and has to overcome the handicap of the rim.
However, the difference between two pistols in this regard is often bigger than the difference bewtween the two cartridges.
Given a pocket pistol in each caliber, one as reliable a feeder as the other, I'd take the 25 ACP, as the centerfire primer is more reliable than the rimfire.
Serice sized target pistols seem to do pretty good at feeding the 22 LR because among other reasons, they sre of better quality than the average run of pocket pistols.