These data are from the Hogdon website:
http://www.hodgdon.com/data/pistol/454casul.phpI offer this as an example of how a bit more pressure might not give that much extra terminal performance. I am ignoring all of the many variables that go into this equation in doing so including the fact that these two loads use different powders. Sorry about that! Please note that these data are given in Copper Units (CUP) which correlates with but isn't equal to Pounds Per Square Inch (PSI). In other words, a 10,000 unit difference in CUP is very close to a 10,000 unit difference in PSI.
454 CASULL
CASE: FREEDOM ARMS
BBL: 9.375"
PR: WINCHESTER SR
260 GR. FA JFP
---H110 -- 36.0 -- 1954 -- 51,600 CUP
LIL'GUN -- 35.5 -- 1895 -- 37,900 CUP
Here we see two loads. The lower pressure load is 13,700 CUP less than the higher pressure load. Yet the lower pressure load is only 59 FPS less.
This is what I meant by my statement that you might not net much performance from that last bit of pressure.