That's a puzzler for sure...
During the past 15+ years I've used Pyrodex RS, Pyrodex P, Goex FFFg, and Goex FFg...in about 20 rifles including inlines, sidelock percussions, and flintlocks, with 209 primers, #11 caps, and 4F priming powder;
In .45/.50/.54/.58/.62 calibers, using patched balls, Hornady Great plains bullets, TC Maxi-Hunters, Hornady Sabot/pistol bullets;
Light target loads, heavy hunting loads, layered loads of Goex & Pyrodex, year round hot & cold temperatures, high & low humidity, etc;
No crud rings no matter what variables I used...the only common denominator through all of that has been the lube...I used Natural Lube 1000 exclusively...seems to be the only difference