You may have a couple things going on here at once. As stated, this involves BOTH your reloads and your rifle.
(No insult to your intelligence meant. I am unsure of your reloading knowledge or experience)
This "ring" is a tell tale sign of head space issue. USUALLY found to be the fault of the guns chamber. It COULD be the reloaded cartridges. It is a result of your brass trying to "fill" the guns chamber. The area just above the web is where it thins, leaving the ring you are finding. Sometimes it is only a pertucular lot of brass and not a major problem. Definitely check those cases. I have a couple questions.
Is this a new to you gun? I mean you are recently shooting reloads in it. Was it purchased new or used? How do FACTORY rounds look? Has this problem ONLY found in your reloads?
Lets rule out the reloads. You will need a case KNOWN to be fired in your rifle. Now accurately measure the case. Compare the measurements to that calibers diagram in your loading manuels. If you find that the shoulder is longer than the sammi specs for that caliber your problem is with your guns chamber. For a idea of a leighway, compare other calibers you may have that are known not to have any problems. Depending on your load, this may NOT be completely accurate. If we suspect the gun, we may need to get an accurate cast of the guns chamber. This is easily done with a material called creosafe, available from Brownells and Midway. You could also force a related bullet to accurately full the chamber, by seating a overly long bullet out to firmly engague the rifling and fire it.
DO NOT DO THIS WITH A REGULAR POWDER CHARGE!!! It needs to be reduced, as we are only looking for chamber dimensions. If the case is too short it is held to the breech face by the extractor. it is slammed to the rear, upon ignition and the case is streached to the front of the chamber by the rapidly expanding gasses. But the extractor is not keeping the case against the breech and brass is somewhat elastic. Seating a bullet long forces the case against the breech, forcing the brass to flow forward, filling the chamber.
In your initial die setup, do you have firm contact between the sizing die and the shell holder? I prefer light contact, but this will be determined more specifically by your particular guns chamber dimensions. Initially, I adjust mine to firm contact, than back them out about 1/2 turn.
I have more suggestions, if you could answer my questions, I'll have a better idea of how to help. I'll check here again tonight night.
Once we know where the problem lies we can better decide on a course of action to deal with it.
CW